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Manganese Borogluconate SDS of Manufacturers

Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty Chemicals, Pharmaceutical Excipients, Fragrance & Flavor Chemicals in India.  Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston, Chicago USA and Dubai, UAE. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, USP, NF, Ph. Eur., JP, FCC or Food Grade, Analytical Reagent Grade, LR or Laboratory Reagent Grades and Pure Grades of various chemicals. All our items are analyzed to meet the required standards.  We can supply the product in grams for your laboratory trial and in tons for your plant scale jobs.

We manufacture Bulk Drugs / API, Excipients, Pharmaceuticals (IP BP USP NF Ph Eur EP JP), Specialty Chemicals (Pure/Reagent), Mineral Fortifiers (FCC).  Our manufacturing facility is FDA approved and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) is available.  Solid materials can be customized for particle size, shape, and bulk density. We observe WHO Good Manufacturing Practices and Good Laboratory Practices. We are a government-recognized STAR Export House and "Authorised Economic Operator (AEO)" per Indian Customs.

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Manganese Borogluconate Specifications of Manufacturers

Manganese Borogluconate Manufacturers

Manganese Borogluconate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
22-Nov-21

1. Product Identification

Product Name & Other Names: Manganese Borogluconate.
CAS No.: Manganese Gluconate: 6485-39-8 Boric acid :10043-35-3
EINECS EC Number: Manganese Gluconate: 229-350-4 + Boric acid: 233-139-2 & 234-343-4
Molecular Formula: Manganese Gluconate: MnC12H22O14 + Boric acid: B(OH)3,
Molecular Weight: Manganese Gluconate: 445.23, Boric acid: 61.83
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

2. Hazards Identification

The toxicology properties of this product are not suitably studied. Although, Calcium Borogluconate is generally classed as non-hazardous, it is safer to go by the Boric Acid properties.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin irritation (Category 2), H315
Eye irritation (Category 2B), H320
Reproductive toxicity Category 1A, 1B, H360

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Health Hazard
Health Hazard

Signal Words: Danger

Hazard statements:
H315 + H320: Causes skin and eye irritation.
H360: May damage fertility or the unborn child.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P281: Use personal protective equipment as required.
P308+313: IF exposed or concerned: Get medical advice/attention.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.
Boric Acid has a low acute toxicity. Small amounts swallowed accidentally are not likely to cause effects; swallowing large amounts may cause gastrointestinal symptoms.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi = Irritant
Xn = Harmful.
Risk Phrase:
R36/38- Irritating to eyes and skin.
R61 = May cause harm to the unborn child.
R62- Possible risk of impaired fertility.

3. Composition/Information on Ingredients

Product Name & Other Names: Manganese Borogluconate.
CAS No.: Manganese Gluconate: 6485-39-8 Boric acid :10043-35-3
EINECS EC Number: Manganese Gluconate: 229-350-4 + Boric acid: 233-139-2 & 234-343-4

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt, or waistband. Get medical attention if symptoms appear.
Skin Contact: Remove any contaminated clothing. Wash skin with soap or mild detergent and water for at least 15 minutes. Get medical attention if irritation develops or persists. Wash cloths and Shoes before re-use.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
Note to physicians: Observation only is required for adult ingestion of less than 6 grams of boric acid. For ingestion more than 6 grams, maintain adequate kidney function and force fluids. Gastric lavage is recommended for symptomatic patients only. Hemodialysis should be reserved for massive acute ingestion or patients with renal failure.

5. Fire Fighting Measures

Fire: It is not considered to be a fire hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special hazards arising from the substance or mixture: Borane/boron oxides, Manganese oxide, Carbon oxides and Fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal  authority requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
Occupational exposure limits for dust (total and resizable) are treated by OSHA, Cal OSHA and ACGIH as “Particulate Not Otherwise Classified” or “Nuisance Dust”
ACGIH/TLV 10 mg/m3; Cal OSHA/PEL 10 mg/m3; OSHA/PEL (total dust) 15 mg/m3; OSHA/PEL (respirable dust) 5 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g., lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Gloves and lab coat, apron, or coveralls.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Appearance: White to yellow tinged white crystalline or granular powder.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Formula: Manganese Gluconate: MnC12H22O14 + Boric acid: B(OH)3,
Molecular Weight: Manganese Gluconate: 445.23, Boric acid: 61.83

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage. Avoid moisture, heat, light.
Hazardous Decomposition Products: Borane/boron oxides, Magnesium oxide, Carbon oxides and Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents. Avoid moisture, heat, light.

11. Toxicological Information

Toxicological Data:
For Boric Acid: Oral rat LD50: 2660 mg/kg; LD50 in rabbits is greater than 2,000 mg/kg of body weight.
For Manganese Gluconate: Acute oral toxicity (LD50): 5850 mg/kg [Rat].
Oral woman LDLo: For Boric Acid: 200 mg/kg; investigated as a mutagen, tumorigen, reproductive effector.
Reproductive Toxicity: May impair fertility. May cause harm to the unborn child.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.

12. Ecological Information

Toxicity to fish:
For Boric Acid
:
LC50 - Ptychocheilus lucius - 279 mg/l - 96 h; LC0 - Lepomis macrochirus (Bluegill) - > 1.021 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates:
For Boric Acid
: LC50 - Daphnia magna (Water flea) - 53,2 mg/l - 21 d
For Boric Acid: EC50 - Daphnia magna (Water flea) - 133 mg/l - 48 h
Environmental Toxicity: This material may be harmful to aquatic life.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods
IMDG/IMO & IATA: Not dangerous goods.

15. Regulatory Information

It should be noted that borates are safe under conditions of normal handling and use, besides, they are essential nutrients to plants, and research shows that they play a beneficial role in health.

USA:
SARA 311/312
: Chronic Health Hazard. See section 2.
California Prop. 65 Components: Not listed.

16. Other Information

European Labeling in Accordance with EC Directives:
H315 + H320: Causes skin and eye irritation.
H360: May damage fertility or the unborn child.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi = Irritant
Xn = Harmful.
Risk Phrase:
R36/38- Irritating to eyes and skin.
R61 = May cause harm to the unborn child.
R62- Possible risk of impaired fertility.

Disclaimer:
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Our company provides this SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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TEL: (OFF) +91 22 23726950, +91 22 23774610, +91 22 23723564

e-mail: info@anmol.org

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Last updated 27-mar-22

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