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Glacial Acetic Acid SDS of Suppliers

Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty chemicals, Pharmaceutical Excipients, Fragrance & Flavor chemicals in India. Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston Chicago USA and toll manufacturers in China. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, USP, Ph. Eur., FCC or Food Grade, ACS, AR or Analytical Reagent Grade, LR or Laboratory Reagent Grade, Pure and Technical Grades of various chemicals. All our items are analyzed to meet the required standards.

Our manufacturing facility is FDA approved and GMP, ISO-9001-2008, ISO-14001, ISO OHSAS 18000, ISO 22000-2005 HACCP, FSSAI, FSSC-22000, certified. We are offering products manufactured as per Kosher and Halal approved certified method. We are pre-registered with "Reach" for export to European countries. We can give all solid chemical materials as per specified size or shape.

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Glacial Acetic Acid Specifications of Manufacturers

Glacial Acetic Acid

Glacial Acetic Acid SDS MSDS Sheet, Material Safety Data Sheet

Section 1 - Chemical Product and Company Identification

MSDS Name: Acetic Acid
Synonyms: Ethanoic acid, Ethylic acid, Methanecarboxylic acid, Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Molecular Formula: CH3COOH
Molecular Weight: 60.05
Recommended usage
: Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2 - Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids (Category 3) H227
Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Combustible Liquid
Combustible Liquid

GHS Label Elements
Corrosive
Corrosive

Signal Words (GHS-US): Danger

Hazard statements (GHS-US):
H227: Combustible liquid.
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.

Precautionary statements (GHS-US):
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313: If eye irritation persists: Get medical advice/ attention.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P273: Avoid release to the environment.
P501: Dispose of contents/container to comply with local, state and federal regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
C Corrosive
R10 Flammable.
R35 Causes severe burns.
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

Section 3 - Composition/Information on Ingredients

Chemical Name: Acetic Acid
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Percent
: 99-100% on dry basis. Dilution is always with water

Section 4 - First Aid Measures

Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: 40C 104F
Auto Ignition Temperature: 463C 865F
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.

Section 6 - Accidental Release Measures

Spills/Leaks: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Contain the spill with sand or other inert absorbent material, neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container of Acetic acid tightly closed. Avoid ingestion and inhalation. Do not allow contact with heat. Do not breathe vapors or spray mist.
Storage: Store Acetic acid in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store Acetic acid protected from heat and flames.

Section 8 - Exposure Controls, Personal Protection

Airborne Exposure Limits: Airborne Exposure Limits:
OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA).
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL).
NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Acetic acid.

Section 9 - Physical and Chemical Properties

Appearance: Clear Liquid
Odor: Vinegar odor
Solubility: Soluble in water
Specific Gravity: 1.049
pH: 2 for 1% solution, 2.4 (1.0M solution)
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 118.°C (244.5°F)
Melting Point:
16.6°C (61.9°F)
Molecular Formula:C2H4O2
Molecular Weight:60.05

Section 10 - Stability and Reactivity

Chemical Stability: Acetic acid is stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to heat, spark, moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

Acute oral toxicity (LD50): 3310 mg/kg [Rat].
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit].
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse].
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.

Section 12 - Ecological Information

Environmental Fate: The material will readily biodegrade.
Environmental Toxicity: (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia].

Section 13 - Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Acetic acid and unused contents in accordance with local requirements.

Section 14 - Transport Information

DOT (US) and ADR/RID
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs
Marine pollutant: No
IATA
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial

Section 15 - Regulatory Information

USA:
TSCA
: CAS# 64-19-7 is listed on the TSCA inventory.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Health & Safety Reporting List: None of the chemicals are on the List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals have a SNUR under TSCA.
SARA Section 302 (RQ): CAS# 64-19-7: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: CAS# 64-19-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
HMIS (Perceived): Health Hazard: 3; Fire Hazard: 2; Reactivity: 0; Personal Protection: E
NFPA (Perceived): Health: 3; Flammability: 2; Reactivity: 0;
STATE: CAS# 64-19-7 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Canada:
CAS# 64-19-7 is listed on Canada's DSL List.
This product has a WHMIS classification of B3, E.
CAS# 64-19-7 is listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives
EINECS
: 200-580-7.
H227 = Combustible liquid.
H314 = Causes severe skin burns and eye damage.
H402 = Harmful to aquatic life.
C = Corrosive
R10 = Flammable.
R35 = Causes severe burns.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Manufacturers

ANMOL CHEMICALS
Taloja Mumbai and Ankleshwar Gujarat, INDIA
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) 91-22-23726950, 23774610, 23723564

e-mail: info@anmol.org

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Last updated 28-jun-18

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