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Dibutyltin Diacetate SDS of Manufacturers

Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty Chemicals, Pharmaceutical Excipients, Fragrance & Flavor Chemicals in India.  Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston, Chicago USA and Dubai, UAE. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, USP, NF, Ph. Eur., JP, FCC or Food Grade, Analytical Reagent Grade, LR or Laboratory Reagent Grades and Pure Grades of various chemicals. All our items are analyzed to meet the required standards.  We can supply the product in grams for your laboratory trial and in tons for your plant scale jobs.

We manufacture Bulk Drugs / API, Excipients, Pharmaceuticals (IP BP USP NF Ph Eur EP JP), Specialty Chemicals (Pure/Reagent), Mineral Fortifiers (FCC).  Our manufacturing facility is FDA approved and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) is available.  Solid materials can be customized for particle size, shape, and bulk density. We observe WHO Good Manufacturing Practices and Good Laboratory Practices. We are a government-recognized STAR Export House and "Authorised Economic Operator (AEO)" per Indian Customs.

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Dibutyltin Diacetate Specifications of Manufacturers

Dibutyltin Diacetate Manufacturers

Dibutyltin Diacetate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 16-Jan-22

1. Product Identification

Product Name & Other Names: Dibutyltin diacetate, Di-n-butyl Tin Di Acetate, DDTDA, Diacetoxybutyltin, Diacetoxydibutyltin.
CAS No.: 1067-33-0
EINECS Number: 213-928-8
Molecular Weight: 351.03
Chemical Formula: C12H24O4Sn or (CH3CH2CH2CH2)2Sn(OCOCH3)2
Relevant uses and uses advised against (if any): Laboratory Chemicals and Industrial Manufacturing Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute oral toxicity Category 4, H302
Skin corrosion Category 1B, H314
Skin sensitization Category 1, H317
Germ cell mutagenicity Category 2, H341
Reproductive toxicity Category 1B, H360
Specific target organ toxicity - single exposure, Oral Category 1, thymus gland, H370
Specific target organ toxicity - repeated exposure Category 1, H372
Long-term (chronic) aquatic hazard Category 1, H410

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
Marine Pollutant
Marine Pollutant

Signal Word: Danger

Hazard statements:
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H341: Suspected of causing genetic defects.
H360: May damage fertility or the unborn child.
H370: Causes damage to organs.
H372: Causes damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C, Corrosive
Xn, Harmful
N, Dangerous for the environment
Risk Phrase:
R20/21/22/48 Harmful : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R34 Causes burns
R41 Risk of serious damage to eyes
R46 May cause inheritable genetic damage
R43 May cause sensitization by skin contact
R 63 Possible risk of harm to the unborn child.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. Composition/Information on Ingredients

Product Name & Other Names: Dibutyltin diacetate, Di-n-butyl Tin Di Acetate, DDTDA, Diacetoxybutyltin, Diacetoxydibutyltin.
CAS No.: 1067-33-0
EINECS Number: 213-928-8

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used. Wash clothing & Shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Flash Point: >110C
Auto-ignition Temperature: >500C
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Decomposition Products: Carbon oxides, Tin/tin oxides, Fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Soak up with inert absorbent material. Use appropriate tools to put the spilled material in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids. and bases.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
ACGIH TLV (TWA): 0.1 mg(Sn)/m3
ACGIH TLV (STEL): 0.2 mg(Sn)/m3
OSHA PEL (TWA): 0.1 mg (Sn)/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Engineering Controls: Showers, Eyewash stations, Ventilation systems.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Colorless liquid.
Odor: Acetic.
Odor threshold: Not available.
pH: Not available.
Relative density: about 1.31-1.32
Melting Point: 7-10C (literature).
Boiling Point: 142-145C (literature)..
Flash Point: >110C
Auto-ignition Temperature: >500C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Negligible soluble in water.
Viscosity: Not available.
Molecular Weight: 351.03
Chemical Formula: C12H24O4Sn or (CH3CH2CH2CH2)2Sn(OCOCH3)2

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Forms explosive mixtures with air on intense heating.
Hazardous Decomposition Products: Carbon oxides, Tin/tin oxides. Toxic fumes may be released when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidants, acids. and bases.
Conditions to Avoid: Heat Moisture and Incompatibles.

11. Toxicological Information

Acute toxicity:
LD50 Oral - Rat - >900 mg/kg.
LD50 Dermal - Rat - >2000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC, NTP and OSHA.
Reproductive toxicity: May impair fertility. May cause harm to the unborn child.
Developmental Effects: No information found.
Germ cell mutagenicity: No information found.
Teratogenicity: No information found.

12. Ecological Information

Toxicity to fish: LC50 - Oryzias latipes - 3 mg/l - 48.0 h.
Toxicity to daphnia & other aquatic invertebrates: EC50 - Daphnia (water flea) - 1.4 mg/l - 48 h.
Environmental Toxicity: Toxic to aquatic organisms, may cause long-term adverse effects.
Mobility: No information found.
Results of PBT and vPvB assessment: Not available.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

14. Transport Information

DOT USA & ADT/RID Europe:
UN number: 2922, Class: 8 (6.1), Packing group: II
Proper shipping name: Corrosive liquid, toxic, n.o.s. (Dibutyltin diacetate)
IMDG & IATA:
UN number: 2922, Class: 8 (6.1), Packing group: II
Proper shipping name: Corrosive liquid, toxic, n.o.s. (Dibutyltin diacetate).

15. Regulatory Information

USA:
SARA 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard.
SARA Section 313: Substance is not listed.
California Proposition 65: This product does not contain Proposition 65 chemicals.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H341: Suspected of causing genetic defects.
H360: May damage fertility or the unborn child.
H370: Causes damage to organs.
H372: Causes damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C, Corrosive
Xn, Harmful
N, Dangerous for the environment
Risk Phrase:
R20/21/22/48 Harmful : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R34 Causes burns
R41 Risk of serious damage to eyes
R46 May cause inheritable genetic damage
R43 May cause sensitization by skin contact
R 63 Possible risk of harm to the unborn child.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Manufacturers

ANMOL CHEMICALS
Taloja Mumbai and Ankleshwar, INDIA
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) +91 22 23726950, +91 22 23774610, +91 22 23723564

e-mail: info@anmol.org

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Last updated 26-mar-22

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