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Calcium Sulfate Sulphate Hemihydrate Anhydrous SDS of Suppliers

Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty chemicals, Pharmaceutical Excipients, Fragrance & Flavor chemicals in India. Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston Chicago USA and toll manufacturers in China. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, USP, Ph. Eur., FCC or Food Grade, ACS, AR or Analytical Reagent Grade, LR or Laboratory Reagent Grade, Pure and Technical Grades of various chemicals. All our items are analyzed to meet the required standards.

Our manufacturing facility is FDA approved and GMP, ISO-9001-2008, ISO-14001, ISO OHSAS 18000, ISO 22000-2005 HACCP, FSSAI, FSSC-22000, certified. We are offering products manufactured as per Kosher and Halal approved certified method. We are pre-registered with "Reach" for export to European countries. We can give all solid chemical materials as per specified size or shape.

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Calcium Sulfate Specifications of Manufacturers

Calcium Sulfate Dihydrate SDS of Manufacturers

Calcium Sulfate Sulphate BP IP USP ACS Analytical Reagent FCC Food Grade Manufacturers

Calcium Sulphate Hemihydrate Anhydrous SDS MSDS Sheet, Material Safety Data Sheet

Section 1: Chemical Product and Company Identification

Product Name: Calcium sulfate hemihydrate or Calcium sulfate anhydrous
CAS #:
10034-76-1 for hemihydrate or 7778-18-9 for anhydrous
EINECS EC number
: 231-900-3
Chemical Name:
Calcium sulfate, hemihydrate or Calcium Sulfate anhydrous
Chemical Formula: CaSO4-0.5H2O or CaSO4
Relevant Uses: Industrial use only.
Supplier: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

OSHA Hazards: No known OSHA hazards.
WHMIS classification is not included based on the recommended option (Option 4) found in the Canada Gazette Part II, Vol. 149, No.3, page 458

Section 3: Composition and Information on Ingredients

Name: Calcium sulfate hemihydrate or Calcium sulphate anhydrous
CAS #: 10034-76-1 for hemihydrate or 7778-18-9 for anhydrous
% by Weight: 100

Section 4: First Aid Measures

Always seek medical advice after the first aid treatment.

Calcium sulfate hemihydrate or anhydrous or Calcium sulphate hemihydrate or anhydrous is harmful if swallowed. May cause irritation. Avoid breathing vapors, or dusts. Use with adequate ventilation. Avoid contact with eyes, skin, and clothes. Wash thoroughly after handling. Keep container closed.
FIRST AID: CALL A PHYSICIAN. SKIN: Wash exposed area with soap and water.
EYES: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
INGESTION: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Slightly explosive in presence of heat.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Remarks on Fire Hazards: Calcium sulphate hemihydrate or anhydrous mixed with phosphorus will ignite at high temperatures.
When primed at high temperature with potassium nitrate-calcium silicide mixture, calcium sulfate mixed with excess red phosphorus will burn.
When heated to decomposition it emits toxic fumes of oxides of sulfur and calcium.
Special Remarks on Explosion Hazards Many metal oxo-compounds (nitrates, oxides, and particularly sulfates) and sulfides are reduced violently or explosively (undergo a thermite reaction) on heating an intimate mixture with aluminum powder to a suitably high temperature to initiate the reaction. A violent or explosive reaction can occur upon heating when calcium sulfate is mixed with aluminum powder.
Containers of Calcium sulfate or Calcium sulphate may explode when heated.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of Calcium sulfate according to legal requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Avoid contact with moisture.

Section 7: Handling and Storage

Precautions: Do not breathe dust of Calcium sulfate. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container of Calcium sulphate or anhydrous tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic. Avoid moisture.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits:
TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total.
TWA: 5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.
TWA: 10 (mg/m3) from ACGIH (TLV) [United States]
TWA: 10 (mg/m3) [United Kingdom (UK)] Inhalation Total.
TWA: 4 (mg/m3) [United Kingdom (UK)] Inhalation Respirable.3
Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Calcium Sulphate hemihydrate or anhydrous is solid. (hygroscopic crystals; lumps; powder)
Odor: Odorless.
Color: White.
pH (1% soln/water): Not available.
Melting Point: Not available.
Critical Temperature: Not available.
Molecular Weight: 145.15 for hemihydrate and 136.14 for anhydrous
Molecular Formula: CaSO4.0.5H2O for hemihydrate and CaSO4 for anhydrous
Solubility: Very slightly soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: Calcium sulfate hemihydrate or anhydrous is stable.
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Hygroscopic; keep container tightly closed. Loses waters at 163 C. Incompatible with Diazomethane, aluminum, magnesium, phosphorous.
Polymerization: Will not occur.

Section 11: Toxicological Information

Toxicity to Animals:
LD50 (Oral) Rat 3,920 mg/kg           
LC50: Not available.
Special Remarks on Toxicity to Animals:
The probable lethal oral human dose has been estimated to be 0.5 to 5 g/kg.

Section 12: Ecological Information

Ecotoxicity:
Calcium sulphate, dihydrate EC50 >79 mg/l Algae 72 hours
EC50 >79 mg/l Daphnia 48 hours
EC50 >790 mg/l Micro-organism 3 hours
Acute LC50 >1970 mg/l Fish 96 hours
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Section 13: Disposal Considerations

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT (US): Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

Section 15: Other Regulatory Information

USA Regulations:
OSHA Hazards: No known OSHA hazards
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
Massachusetts Right To Know Components: Calcium sulfate, CAS-No. 10101-41-4
Pennsylvania Right To Know Components: Calcium sulfate, CAS-No. 10101-41-4
New Jersey Right To Know Components: Calcium sulfate, CAS-No. 10101-41-4
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Illinois toxic substances disclosure to employee act: Calcium sulfate dihydrate
Rhode Island RTK hazardous substances: Calcium sulfate dihydrate

HMIS (Perceived): Health Hazard: 1, Fire Hazard: 0, Reactivity: 0, Personal Protection: E
NFPA (Perceived): Health: 1, Flammability: 0, Reactivity: 0

Canada WHMIS: Not controlled under WHMIS (Canada).

EINECS EC number: 231-900-3

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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Manufacturers

ANMOL CHEMICALS
Taloja Mumbai and Ankleshwar Gujarat, INDIA
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) 91-22-23726950, 23774610, 23723564

e-mail: info@anmol.org

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Last updated 25-sep-18

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