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Calcium Nitrite Solution SDS of Suppliers
Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty chemicals, Pharmaceutical Excipients, Fragrance & Flavor chemicals in India. Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston Chicago USA and toll manufacturers in China. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, USP, Ph. Eur., FCC or Food Grade, ACS, AR or Analytical Reagent Grade, LR or Laboratory Reagent Grade, Pure and Technical Grades of various chemicals. All our items are analyzed to meet the required standards.
Our manufacturing facility is FDA approved and cGMP, ISO-9001, ISO-14001, ISO OHSAS 18000, ISO 22000-2005 HACCP, FSSAI, FSSC-22000, certified. Apart from good manufacturing practice, we also follow good laboratory practice. We are offering products manufactured as per Kosher and Halal approved certified method. We are pre-registered with "Reach" for export to European countries. We can give all solid chemical materials as per specified size or shape.
Calcium Nitrite CAS No.: 13780-06-8, Molecular Weight: 132, Chemical Formula: Ca(NO2)2
Calcium Nitrate CAS No.: 13477-34-4, Molecular Weight: 236.15, Chemical Formula: Ca(NO3)2-4H2O
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Calcium Nitrate SDS of Manufacturers
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Calcium Nitrite Solution SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Solution of Calcium Salt of Nitrous Acid, Solution of Calcium dinitrite.
CAS No.: 13780-06-8 (as Anhydrous Calcium Nitrate)
EINECS: EC Number: 237-424-2.
Molecular Weight: 132.09
Chemical Formula: Ca(NO2)2 ( Calcium Nitrite Anhydrous)
Relevant Uses: Concrete antifreeze, quick set agent and rust-proofing reinforced steel bar & Industrial use only.
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: Warning
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May Causes mild eye irritation.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P273: Avoid release to the environment.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
HMIS (Perceived): Health: 2, Flammability: 0, Reactivity: 0, Personal Protective Equipment: B (See Section 8)
NFPA (Perceived): Health: 2, Flammability: 1, Reactivity: 0
3. Composition/Information on Ingredients
Ingredient: Calcium Nitrite Solution 30-33% with Calcium Nitrate 0 to 2% in water.
CAS No.: 13780-06-8
EINECS: EC Number: 237-424-2.
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable. However the product supports combustion.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: When heated to decomposition, emits acid fumes.
Fire: Calcium Nitrite Solution is not considered to be a fire hazard though it supports combustion as an oxidizer.
Explosion: Containers may explode in the heat of a fire.
Fire Extinguishing Media: Preferably use water sprat. Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Calcium Nitrite Solution is a Strong Oxidizer. May decompose explosively when heated or involved in a fire. May accelerate burning if involved in a fire.
6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.
7. Handling and Storage
Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Calcium Nitrite Solution in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Calcium Nitrite Solution is colorless to off-white.
Odor: It is odorless to slight sweet odor.
Solubility: It is freely soluble in water.
Density: : Varies with %. Dry substance is 2.26 gm/cc.
Molecular formula: Ca(NO2)2 in water
Molecular weight: 132.09 for Ca(NO2)2
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not known.
Melting Point: 390C.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
10. Stability and Reactivity
Stability: Calcium Nitrite Solution is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic acid fumes when heated to decomposition. Nitrogen oxides (NOx), Calcium oxide are formed.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reactive with reducing agents, organic materials. The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.
Conditions to Avoid: Incompatibles. Avoid contact with combustible material (paper, wool, oil).
11. Toxicological Information
Routes of Entry: Inhalation, Ingestion, Eye Contact.
Toxicity to Animals: LD50 (Oral-Rat) 940 mg/kg. (Variously reported)
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: IARC: 2A - Group 2A: Probably carcinogenic to humans.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
BOD5 and COD: Not available.
Environmental Fate: Based on available information Calcium Nitrite Solution will not biodegrade or bio accumulate.
Environmental Toxicity: The product may be harmful to plants, animals and fish.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
Proper Shipping Name: Nitrites, Inorganic, (Calcium Nitrite Solution)
U.N. No.: 2627
Hazard Class and Packing Group Number: 5.1, PG II
Marine Pollutant: NO
15. Regulatory Information
OSHA: Not Listed
CERCLA: (RQ) Not Listed
SARA Title III Information:
Extremely Hazardous Substance: Not Listed
Toxic Chemicals: Not Listed
New Jersey - Right to Know Hazardous: Substance List: Calcium Nitrite.
California Proposition 65: This product does not contain substances known to the state of California to cause cancer, birth defects or other reproductive harm.
US SARA reporting requirements: The components of this product are subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, and are listed as follows:
Chemical Name Calcium Nitrite Solution (as Nitrite Compounds, Water Dissociable)
SARA 302 (40 CFR 355, Appendix A) No
SARA 304 (40 CFR Table 302.4) No
SARA 313 (40 CFR 372.65) Yes
US SARA Threshold Planning quantity: There are no specific Threshold Planning Quantities for the components of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20.
US SARA Hazard categories (section 311/312, 40 CFR 370-21): Acute: Yes; Chronic: Yes; Fire: No; Reactive: No; Sudden Release: No
US TSCA Inventory Status: The components of this product are on the U.S. TSCA Inventory.
Canadian DSL Inventory: The components of this product are on the NDSL, DSL Inventory.
Canadian WHMIS Symbols: Class D2B: Materials Causing Other Toxic Effects.
EINECS: EC Number: 237-424-2.
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Taloja Mumbai and Ankleshwar Gujarat, INDIA
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) 91-22-23726950, 23774610, 23723564
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Last updated 14-jan-19
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