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Heavy Bismuth Subnitrate SDS of Manufacturers Suppliers

Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty chemicals, Pharmaceutical Excipients, Fragrance & Flavor chemicals in India. Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston Chicago USA, Dubai and UAE. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, USP, Ph. Eur., FCC or Food Grade, Analytical Reagent Grade, LR or Laboratory Reagent Grade, Pure and Technical Grades of various chemicals. All our items are analyzed to meet the required standards. We can supply the material in grams for your laboratory trial and in tons for your plant scale jobs.

Our manufacturing facility is FDA approved and cGMP, GLP (FDA) Approved, ISO 9001, ISO 14001, ISO 17025, ISO 45001, ISO 22000, HACCP, FSSAI, FSSC 22000, Halal and Kosher certified. We are registered with "REACH" for export to European countries. Solid materials can be customized for particle size, shape and bulk density. We observe WHO Good Manufacturing Practice and Good Laboratory Practice. We are a STAR Export House and “Authorised Economic Operator” as per Indian customs.

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Heavy Bismuth Subnitrate Specifications of Manufacturers

Heavy bismuth subnitrate Manufacturers

Heavy Bismuth Subnitrate or Bismuth Nitrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Product Name & Other Names: Heavy bismuth subnitrate or Bismuth (III) nitrate basic or Bismuthyl nitrate or Bismuth(III) oxynitrate or Bismuth(III) subnitrate
CAS No.: 1304-85-4
EINECS EC Number: 215-136-8
Molecular Weight: 1461.99
Chemical Formula: Bi5O(OH)9(NO3)4
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3, H272
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335
Hazardous to the aquatic environment, acute hazard Category 3, H402

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizing Solid
Oxidizing Solid

GHS Label Elements
Irritant
Irritant

Signal Word: Warning

Hazard Statements:
H272: May intensify fire; oxidizer.
H315 : Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Dry chemical, carbon dioxide, Halon, water spray, or fog for extinction. If water is used, apply from as far a distance as possible.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
O Oxidizing
Xi Irritant
Risk Phrase:
R8 Contact with combustible material may cause fire.
R36/37/38 Irritating to eyes, respiratory system and skin.
R52 Harmful to aquatic organisms.

3. Composition/Information on Ingredients

Product Name & Other Names: Heavy bismuth subnitrate or Bismuth (III) nitrate basic or Bismuthyl nitrate or Bismuth(III) oxynitrate or Bismuth(III) subnitrate
CAS No.: 1304-85-4
EINECS EC Number: 215-136-8

4. First Aid Measures

Always seek medical advice after the first aid treatment.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

5. Fire Fighting Measures

Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Explosion: Some nitrates may explode when shocked, exposed to heat or flame, or by spontaneous chemical reaction. Sealed containers may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media: Dry chemical, carbon dioxide, Halon, water spray, or fog. If water is used, apply from as far a distance as possible. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways.
Special Information: Wear full protective clothing and breathing equipment for high-intensity fire or potential explosion conditions. This oxidizing material can increase the flammability of adjacent combustible materials.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong reducing agents, alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Keep away from sources of ignition - No smoking.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Solid.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 4.93
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): Negligible @ 20C.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water
Viscosity: Not available.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of bismuth and nitrogen and toxic metal fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

Oral rat LD50: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity data: Not available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. Dispose of container and unused contents in accordance legal requirements.

14. Transport Information

Domestic (Land, D.O.T.)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
International (Water, I.M.O.)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
International (Air, I.C.A.O.)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II

15. Regulatory Information

USA:
SARA 302
: No
SARA 313: No
SARA 311/312: Acute: No; Chronic: No; Fire; Yes; Pressure: No; Reactivity: No  (Pure / Solid)
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H272 = May intensify fire; oxidizer.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
H402 = Harmful to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
O Oxidizing
Xi Irritant
Risk Phrase:
R8 Contact with combustible material may cause fire.
R36/37/38 Irritating to eyes, respiratory system, and skin.
R52 Harmful to aquatic organisms.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Manufacturers

ANMOL CHEMICALS
Taloja Mumbai and Ankleshwar, INDIA
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) +91 22 23726950, +91 22 23774610, +91 22 23723564

e-mail: info@anmol.org

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Last updated 31-mar-21

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